By Anthony J. Pearson, William R. Roush
Recognising the necessity for a price powerful reference paintings that bargains not just with the most well-liked reagents in synthesis but additionally reaches the widest attainable viewers of practicing natural chemists, the editors of 'The Encyclopedia of Reagents for natural Synthesis' (EROS) have constructed a listing of crucial and worthy reagents hired within the box, with ease awarded in 4 separate volumes. The reagents integrated during this quantity replicate the truth that holding teams and activation methods are frequently utilized in mix. there are lots of situations within the synthesis of usual and unnatural items, prescription drugs, oligosaccharides, and oligonucleotides, etc., the place comparable strategies needs to be hired to avoid undesired activation or response of performance. hence, crucial reagents used to guard amines, alcohols, carboxyl, carbonyl and different reactive sensible teams are incorporated during this quantity. The record of activating brokers contains popular reagents that turn on practical teams for substitution or removing reactions, in addition to much less conventional examples, e.g. HMPA used to "activate" enolates and alkyllithium reagents to extend the nucleophilicity. each one article includes the entire info present in EROS in addition to multiplied similar reagents listings and extra references to let the reader to fast entry a extensive variety of data that's past the scope of the reagent entries themselves. this article is going to end up a useful source.
Read Online or Download Activating agents and protecting groups PDF
Best symmetry and group books
- 359th Fighter Group
- Introduction to arithmetic groups
- Fuchsian groups
- Renormalization group and singular perturbations
- 2-Local subgroups of Fischer groups
- Group Theory. Exceptional Lie groups as invariance groups
Extra info for Activating agents and protecting groups
Alper, H. JOC 1981, 46, 2899. 221. ; Katchalski, E. JOC 1951, 16, 1025. 222. Hoffmann, H. M. ; Haase, K. S 1981, 715. 223. ; Fukumoto, K. H 1992, 33, 851. 224. ; Wannagat, U. M 1962, 93, 352. (b)Bowser, J. ; Williams, P. ; Kurz, K. JOC 1983, 48, 4111. 225. ; Iqbal, J. TL 1986, 27, 3791. Bruce A. 44 g c m - 3 . g. benzene, nitroben zene, carbon tetrachloride, chloroform, methylene chloride, nitromethane, and 1,2-dichloroethane; insol carbon disulfide. 0 M nitrobenzene solution. Handling, Storage, and Precautions: fumes in air with a strong odor of HC1.
20. 21. 22. 23. 24. (a) Eaborn, C. JCS 1956, 4858. ; Effenberger, F. S 1979, 841. ; Pearce, A. CC 1975, 633. (b) Fristad, W. ; Dime, D. ; Bailey, T. ; Paquette, L. A. TL 1979, 1999. (a) Walton, D. R. ; Waugh, F. JOM 1972, 37, 45. (b) Newman, H. JOC 1973, 38, 2254. Karpf, M. TL 1982, 23, 4923. ; Metcalf, B. W. TL 1978, 1581. 25. ; Peterson, P. E. JOC 1980, 45, 5006. 26. 27. ; Kuwajima, I. JOC 1984, 49, 1140. Ferrario, E. BSF 1911, 9, 536. 28. (a) Blatt, A. H. OR 1942, 7, 342. (b) Gammill, R. B. TL 1985, 26, 1385.
Reddy, A. V. TL 1979, 2625. (c) Snider, B. B. ACR 1980, 13, 426. 45. (a) Bingham, R. C; Schleyer, P. R. Top. Curr. Chem. 1971, 18, 1. (b) McKervey, M. A. CSR 1974, 3, 479. (c) McKervey, M. A. T 1980, 36, 971. 46. ; Shima, K. JACS 1989, 111, 3707. 47. ; Calas, R. TL 1976, 2449. ; Calas, R. TL 1976, 1871. 9. ; Shah, V. ; Kruse, L. I. JCS(P1) 1989, 1705. 10. ; Tisler, M. JOC 1966, 31, 4297. (b) Coates, W. ; McKillop, A. JOC 1990, 55, 5418. 11. ; Koyama, K. CC 1985, 287. 48. ; Taddai, M. JOC 1988, 55, 911.
Activating agents and protecting groups by Anthony J. Pearson, William R. Roush